Barely Significant

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Since Vickers hardness tests are always carried out on an area of microstructure, it must be assumed that these stochastically distributed ferrite or martensite grains influence the recorded hardness value, which explains the partially significant standard deviations of the measured values after the tempering tests or even generally irregular results as demonstrated by Figure 11 .
However, there were more significant differences in shear stiffness, and the shear stiffness of the specimens showed a decreasing trend after freeze–thaw cycles; this was due to the damage of the bonding surface caused by the freeze–thaw cycles, resulting in a decrease in the bond strength, and at the same time, the slippage between the steel pipe and the concrete increased; the shear stiffness of the specimens showed an increasing
However, there were more significant differences in shear stiffness, and the shear stiffness of the specimens showed a decreasing trend after freeze–thaw cycles; this was due to the damage of the bonding surface caused by the freeze–thaw cycles, resulting in a decrease in the bond strength, and at the same time, the slippage between the steel pipe and the concrete increased; the shear stiffness of the specimens showed an increasing trend with the increase in concrete strength, which was due to the improvement of concrete strength that increased the mechanical bite force between concrete and steel tube, thereby improving the bond strength of the steel tube push-out specimen and reducing the slip between the concrete and steel tube.
It can be seen from the curves that for each specimen with a specific bonding thickness, with an increase in the node coordinates, the equivalent stress at the interface showed a decreasing trend, showing that under the current specimen parameters (i.e., bonding length and stiffness), the early failure of the left bonding zone was the main cause of the failure of the composite structures.
However, for the distinct peaks (C-H, rocking vibrations, 728 cm −1 ; C-O, stretching vibrations, 1019–1121 cm −1 ; C-O, bending vibrations, 1265 cm −1 ; C=O, stretching vibrations, at 1723 cm −1 ; C-H, stretching vibrations, at 2965 cm −1 ), there was a pronounced trend on decreasing their intensity with enlarging the DRE–plasma exposure time.