Experimental and <i>in silico</i> insights: interaction of dimethyl sulphoxide with 1-hexyl-2-methyl imidazolium bromide/1-octyl-2-methyl imidazolium bromide at different temperatures.

48 With the temperature rise, the molar volume displays an increasing trend due to the mutual loss of dipolar association and the constituent molecules' differences in shape and size ( Table 3 ).

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At 303.15 K, the excess tends to be positive, and after that, a negative trend follows.

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But at higher temperatures, there is a positive trend at all mole fractions of [HMIM][Br].

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